Sulfur isotopes in diamonds reveal differences in continent construction

Pyrite sulfur isotopes reveal glacial-interglacial environmental changes.

The sulfur biogeochemical cycle plays a key role in regulating Earth's surface redox through diverse abiotic and biological reactions that have distinctive stable isotopic fractionations. As such, variations in the sulfur isotopic composition (δ34S) of sedimentary sulfate and sulfide phases over Earth history can be used to infer substantive changes to the Earth's surface environment, including...

Sulfur isotopes of organic matter preserved in 3.45 Gyr- old stromatolites reveal microbial metabolism

Sulfur isotopes of organic matter preserved in 3.45-billion-year-old stromatolites reveal microbial metabolism.

The 3.45-billion-year-old Strelley Pool Formation of Western Australia preserves stromatolites that are considered among the oldest evidence for life on Earth. In places of exceptional preservation, these stromatolites contain laminae rich in organic carbon, interpreted as the fossil remains of ancient microbial mats. To better understand the biogeochemistry of these rocks, we performed microsc...

Interstellar Sulfur Isotopes and Stellar Oxygen Burning

line survey has been made to study interstellar 32 S= 34 S and 34 S= 33 S ratios from the galactic disk. The four CS isotopomers were detected in 20 star forming regions with galactocentric distances between 3 and 9 kpc. From a comparison of line velocities, the C 33 S J=2{1 rest frequency is 250 kHz below the value given in the Lovas (1992) catalog. Taking 12 C= 13 C ratios from Wilson & Rood ...

Sedimentary sulfur isotopes and Neoarchean ocean oxygenation

Abrupt disappearance of mass-independent fractionation of sulfur isotopes (MIF-S) from the geologic record and an apparent ingrowth in seawater sulfate around 2.45 billion years ago (Ga) signal the first large-scale oxygenation of the atmosphere [the Great Oxygenation Event (GOE)]. Pre-GOE O2 production is evident from multiple other terrestrial and marine proxies, but oceanic O2 concentrations...